The role of water in lanthanide-catalyzed carbon-carbon bond formation.

Dynamic measurements of aqueous lanthanide triflate-catalyzed reactions using luminescence decay.

There is tremendous interest in water-compatible lanthanide triflate-based catalysts for carbon-carbon bond forming reactions; however, poor understanding of their aqueous mechanism severely limits the ability to increase the utility of these catalysts. Here, we report dynamic measurements of the water-coordination number of lanthanide triflate-based catalysts using luminescence-decay measureme...

Transition metal-catalyzed functionalization of pyrazines.

Transition metal-catalyzed reactions are generally used for carbon-carbon bond formation on pyrazines and include, but are not limited to, classical palladium-catalyzed reactions like Sonogashira, Heck, Suzuki, and Stille reactions. Also a few examples of carbon-heteroatom bond formation in pyrazines are known. This perspective reviews recent progress in the field of transition metal-catalyzed ...

Influence of Ionic Liquids on Pd-Catalyzed Carbon-Carbon Bond Formation

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates.

The Reactive Chemisorption of Carbon Dioxide at Mg(100) Surface

X-ray photoelectron and electron energy loss spectroscopic (XPS-EELS) studies reveal that the following species are present when a mixture of CO2 and water vapour is exposed to the clean Mg(100) surface at 110K: CO3(a), C(a) CH(a), OH(a). The reactive chemisorptions of CO2 and H2O vapour coadsorbed on a Mg surface ...